| Acids stored with incompatible chemicals | Fire, heat, splashing, or toxic gas release | Acids can react dangerously with bases. Some acids can release highly toxic gases if they contact cyanides or sulfides. | Segregate acids from incompatible materials. Check each product’s Safety Data Sheet (SDS) and follow site-specific chemical-compatibility guidance. |
| Corrosive liquids stored in ordinary shelving | Corrosion, container failure, and spills | Acid vapors or leaks may damage metal shelving and nearby equipment; a weakened shelf or container can lead to a release. | Use a cabinet designed for corrosive chemicals, with materials and fittings suitable for the acids being stored. |
| No secondary containment | Leaked liquid can spread or contact other chemicals | A leaking bottle may flow across a shelf or mix with residue from another container. | Use compatible, chemically resistant trays or other secondary containment. Keep incompatible substances in separate containment areas. |
| Containers left open, damaged, or poorly sealed | Exposure to corrosive liquid or irritating vapors | Loose caps, cracks, or corrosion can allow liquid or vapor to escape during handling and storage. | Keep containers closed when not in use. Inspect them regularly and replace damaged containers using approved procedures. |
| Unclear labels or unknown contents | Incorrect handling or incompatible storage | An unidentified container may be mistaken for a less hazardous chemical or placed beside incompatible materials. | Keep original labels legible. Label transferred containers as required by workplace procedures, and do not store unidentified chemicals. |
| Improper storage of oxidizing acids | Increased fire or reaction risk | Some acids, such as nitric acid, have oxidizing properties and may react with combustible or organic materials. | Review the SDS and compatibility guidance. Store oxidizing acids separately from incompatible chemicals in a suitable designated area. |
| Overloaded or poorly organized cabinet | Dropped containers, spills, and blocked access | Overcrowding can make containers difficult to remove safely and may increase the chance of breakage. | Keep the cabinet within its rated capacity, store containers securely, and maintain clear access for safe handling. |
| Cabinet ventilation changed without review | Unintended exposure or reduced fire protection | Adding an improvised exhaust connection can affect cabinet performance and may not control vapors safely. | Do not modify or ventilate a cabinet unless required by the applicable design, chemical risk assessment, and local safety requirements. |